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Rate of growth of isolated bubbles in sediments with a diagenetic source of methane

dc.contributor.authorBoudreau, Bernard P.en_US
dc.contributor.authorGardiner, Bruce S.en_US
dc.contributor.authorJohnson, Bruce D.en_US
dc.date.accessioned2013-06-19T17:53:23Z
dc.date.available2013-06-19T17:53:23Z
dc.date.issued2001-05en_US
dc.description.abstractObservation of bubbles in estuarine and coastal sediments indicates that bubbles at or below 10 cm depth grow on seasonal time scales (May-October). In order to determine the controls on this growth rate, we have constructed a diffusion-reaction model that accounts for the dynamics of methane formation, its diffusion through pore waters, its incorporation into a bubble, and the consequent growth of the bubble. The model produces an explicit equation for the radius of a growing bubble, R(t), with time using mean parameter values and under the assumption that the mechanics of the sediment response to growth can be neglected: R(t) = [phi D/2c (sub g) {SR (super 2) (sub 1) /3D + (c (sub 1) -c (sub 0) )}t + R (super 2) (sub 0) ] (super 1/2) where phi is the porosity, D is the tortuosity-corrected diffusivity, C (sub g) is the concentration of gas in the bubble, S is the rate of methanogenesis near the bubble, R (sub 1) is the half-separation distance between bubbles (R (sub 1) >>R), c (sub 1) is the ambient CH (sub 4) concentration, c (sub 0) is the pore-water CH (sub 4) concentration at R, t is time, and R (sub 0) is the initial bubble radius, if not zero. The effects of the source S and supersaturation (c (sub 1) -c (sub 0) ), thus, appear as separate contributing terms, and this formula can then be applied even in those cases where apparently c (sub 1) nearly equal c (sub 0) . The model is applied to three sediments where bubbles have been previously studied, i.e., Cape Lookout Bight (USA), White Oak River (USA) and Eckernforde Bay (Germany). In all three cases, using the site-specific time-averaged parameter values, the model predicts seasonal growth rates, consistent with the observations. Furthermore, the source term dominates the rate of growth at the first of these two sites, whereas diffusion from the ambient supersaturation dominates at the German location. Real bubbles may follow a more complicated growth history than predicted by the above equation because of the mechanical properties of sediments; nevertheless, the overall growth times are concordant with ultimate diffusion control. The effects of rectified diffusion, that is, the pumping of gas into a bubble by pressure oscillations, e.g., from waves and tides, were also examined. Existing models for that process suggest that it is negligible, due to the low frequency of these types of oscillations.en_US
dc.identifier.citationBoudreau, Bernard P., Bruce S. Gardiner, and Bruce D. Johnson. 2001. "Rate of growth of isolated bubbles in sediments with a diagenetic source of methane." Limnology and Oceanography 46(3): 616-622.en_US
dc.identifier.issn0024-3590en_US
dc.identifier.issue3en_US
dc.identifier.startpage616en_US
dc.identifier.urihttp://hdl.handle.net/10222/26321
dc.identifier.urihttp://dx.doi.org/10.4319/lo.2001.46.3.0616
dc.identifier.volume46en_US
dc.language.isoenen_US
dc.publisherAmerican Society of Limnology and Oceanography, Ann Arbor, MIen_US
dc.relation.ispartofLimnology and Oceanographyen_US
dc.subjectWhite Oak River estuaryen_US
dc.subjectUnited Statesen_US
dc.subjectDiffusionen_US
dc.subjectMethaneen_US
dc.subjectAliphatic hydrocarbonsen_US
dc.subjectEquationsen_US
dc.subjectAlkanesen_US
dc.subjectCape Lookout Bighten_US
dc.subjectCarteret County North Carolinaen_US
dc.subjectSizeen_US
dc.subjectGasesen_US
dc.subjectModelsen_US
dc.subjectEstuariesen_US
dc.subjectBiogenic processesen_US
dc.subjectOrganic compoundsen_US
dc.subjectDiagenesisen_US
dc.subjectNorth Carolinaen_US
dc.subjectHydrocarbonsen_US
dc.subjectSedimentsen_US
dc.subjectSeasonal variationsen_US
dc.subjectOceanographyen_US
dc.subjectPore wateren_US
dc.titleRate of growth of isolated bubbles in sediments with a diagenetic source of methaneen_US
dc.typearticleen_US

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