Repository logo
 

BODIPYs with Chalcogenophenes at Boron: Synthesis and Properties. Postprint

dc.contributor.authorCampbell, J.W.
dc.contributor.authorTung, M.T.
dc.contributor.authorRobertson, K.N.
dc.contributor.authorBeharry, A.A.
dc.contributor.authorThompson, A.
dc.date.accessioned2023-07-17T22:26:42Z
dc.date.available2023-07-17T22:26:42Z
dc.date.issued2023-07-13
dc.description.abstractReported herein are the synthesis and characterization of BODIPYs bearing heterocycles at boron. To synthesize this series, various chalcogenophenes (furan, thiophene, selenophene, and tellurophene) were lithiated and then used as nucleophiles to attack the boron center of a parent F-BODIPY. Compounds in the series were compared with respect to their photophysical and structural properties, and trends were discussed. By virtue of the “heavy atom effect”, as the mass of the heterocycle appended to the BODIPY core increases, compounds exhibit a higher singlet oxygen quantum yield. The BODIPY with tellurophene at boron exhibits the highest quantum yield (ΦΔ = 0.68) in the series and reduced emission (Φf = 0.01).en_US
dc.identifier.citationBODIPYs with Chalcogenophenes at Boron: Synthesis and Properties Jacob W. Campbell, Matthew T. Tung, Katherine N. Robertson, Andrew A. Beharry, and Alison Thompson The Journal of Organic Chemistry Article ASAP DOI: 10.1021/acs.joc.3c00708en_US
dc.identifier.urihttp://hdl.handle.net/10222/82699
dc.publisherJ. Org. Chem.en_US
dc.relation.ispartofBODIPYs with Chalcogenophenes at Boron: Synthesis and Properties.en_US
dc.titleBODIPYs with Chalcogenophenes at Boron: Synthesis and Properties. Postprinten_US
dc.typeArticleen_US

Files

Original bundle

Now showing 1 - 1 of 1
Loading...
Thumbnail Image
Name:
hets at boron pre-proof accepted version.pdf
Size:
5.07 MB
Format:
Adobe Portable Document Format
Description:

License bundle

Now showing 1 - 1 of 1
No Thumbnail Available
Name:
license.txt
Size:
1.71 KB
Format:
Item-specific license agreed upon to submission
Description:

Collections