Two binding states lattice gas model with multiple interaction: A transfer matrix approach.
| dc.contributor.author | Zhang, Jun. | en_US |
| dc.contributor.degree | Ph.D. | en_US |
| dc.date.accessioned | 2014-10-21T12:37:16Z | |
| dc.date.available | 1992 | |
| dc.date.issued | 1992 | en_US |
| dc.description | The lattice gas model sets up a regular array of points on a plane for particles in the gas phase to adsorb on. In reality, more than one energy levels on a solid surface are available for the ad-particles. Taking the lateral interactions into consideration, things are more complicated: the most probable energy level for an ad-particle to stay may depend on whether there are particles already adsorbed. At certain coverages, the ad-particles may move away from regular surface cell. A two binding states lattice gas model is introduced to simulate the real surface phenomena using transfer matrix method. | en_US |
| dc.description | Frequently examined thermodynamic quantities like coverage, isosteric heat and internal energy are related to the grand canonical partition function of specific systems calculated from the transfer matrix; the desorption rate is expressed in terms of the adsorbate chemical potential under quasi-equilibrium conditions. Using a conventional lattice gas model, we reexamined certain equilibrium properties of 2-d gases on a square lattice, specially we calculated the entropy per site to analyse the possible structures formed on surfaces. We gave the kinetics and dynamics on triangular lattice a systematic study, including multi-interactions. Also examined are equilibrium properties of gases on a honeycomb lattice. | en_US |
| dc.description | Using the two binding states lattice gas model, we fitted the isotherm and desorption trace of CO on a Rhodium (110) surface to a recent experimental result almost perfectly. | en_US |
| dc.description | Thesis (Ph.D.)--Dalhousie University (Canada), 1992. | en_US |
| dc.identifier.other | AAINN80203 | en_US |
| dc.identifier.uri | http://hdl.handle.net/10222/55339 | |
| dc.language | eng | en_US |
| dc.publisher | Dalhousie University | en_US |
| dc.publisher | en_US | |
| dc.subject | Chemistry, Physical. | en_US |
| dc.subject | Physics, Condensed Matter. | en_US |
| dc.subject | Physics, Fluid and Plasma. | en_US |
| dc.title | Two binding states lattice gas model with multiple interaction: A transfer matrix approach. | en_US |
| dc.type | text | en_US |
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