dc.contributor.author | Hilborn, James W. | |
dc.contributor.author | Moya-Barrios, Reinaldo | |
dc.contributor.author | Thompson, Alison | |
dc.date.accessioned | 2019-09-06T12:14:39Z | |
dc.date.available | 2019-09-06T12:14:39Z | |
dc.date.issued | 2019 | |
dc.identifier.citation | Hilborn, James W., Moya-Barrios, Reinaldo, Thompson, Alison. (2019). The Photodecarboxylation of Substituted Naphthylmethyl Arylacetate Esters: Synthesis of Naphthylarylethanes. ACS Publication (pre-publication). | |
dc.identifier.uri | http://hdl.handle.net/10222/76388 | |
dc.description.abstract | The synthesis of naphthylarylethanes via the photodecarboxylation of naphthylmethyl arylacetate
esters is reported where the aryl group is able to stabilize a charge transfer reaction. The reaction
proceeds via intramolecular charge transfer from the donor to acceptor thereby enhancing a
pathway to produce, within the solvent cage, the desired diarylethane products. These in-cage
naphthylarylethanes are produced in good yields, in a single photochemical step, with the use of
cyclohexane as solvent providing optimal yields. | en_US |
dc.relation.ispartof | ACS Publications | en_US |
dc.title | The Photodecarboxylation of Substituted Naphthylmethyl Arylacetate Esters: Synthesis of Naphthylarylethanes | en_US |
dc.type | Article | en_US |