Browsing by Subject "catalysis"
Now showing items 1-6 of 6
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Advances in Nickel-Catalyzed C–O Cross-Coupling Reactions Enabled by Ancillary Ligand Design
(2023-12-04)The ubiquity of C(sp2)–N and C(sp2)–O linkages in active pharmaceutical ingredients, agrochemicals, and other biologically active compounds generates motivation for developing effective avenues for the formation of such ... -
Challenging Nickel-Catalyzed Cross-Couplings Enabled by Ligand Design
(2022-04-05)Carbon-nitrogen linkages are highly prevalent in bioactive molecules, and as such, the development of sustainable methodologies for their formation is of immense importance to both the pharmaceutical and agricultural ... -
The Development of Catalysts for the Monoarylation of Ammonia and Related Challenging Cross-Coupling Reactions
(2013-11-26)The use of homogeneous organometallic catalysis for otherwise challenging chemical transformations is a concept that has gained significant interest in recent decades, providing access to a variety of useful chemical ... -
Expanding the Scope of Nickel-Catalyzed C(sp2)–N/O Cross-Coupling Reactions Using Tailored Ancillary Ligands
(2021-01-18)The ubiquity of aryl C–N/O bonds in pharmaceuticals and natural products necessitates the development of robust and selective methodologies to construct such linkages efficiently. Palladium-catalyzed C(sp2)–N/O cross-coupling ... -
Group 8 and 9 Bis(phosphino)silyl Pincer Complexes: Applications in Bond Activation and Catalysis
(2021-10-18)Advances in homogenous transition metal catalysis are vital for the development of improved, sustainable methodologies in chemical syntheses. Tridentate pincer ligands are highly tunable and are compatible with late 3d-, ... -
A Systematic Investigation into Bisphosphine Ligands for Nickel-Catalyzed C(sp2)–N Cross-Coupling
(2023-04-10)Research into transition metal-catalyzed C–N cross-coupling reactions has been driven by a need for robust and facile synthetic routes towards bioactive molecules which are rich in C–N linkages. The use of Pd-based catalysts ...